ROHF RPA TDDFT Excited Energies Calculation of Sc Failed on Mac using PBE0 and aug-cc-pvdz


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The error is
...
Entering Davidson iterations
Unrestricted

 Iter   NTrls   NConv    DeltaV     DeltaE      Time   
---- ------ ------ --------- --------- ---------
1 10 0 0.15E+00 0.10+100 104.5
------------------------------------------------------------------------
tddft_diagon: negative excitation energy 0
------------------------------------------------------------------------
------------------------------------------------------------------------
current input line :
31: task tddft energy
------------------------------------------------------------------------
------------------------------------------------------------------------
This type of error is most commonly associated with calculations not reaching convergence criteria,
------------------------------------------------------------------------
and the input is
echo
memory total 14000 stack 6500 heap 500 global 7000 mb
charge 0


geometry
 Sc         0.00000000     0.00000000     0.00000000

end


basis spherical
Sc library aug-cc-pvdz
end

scf
rohf
end

dft
xc pbe0
mult 2
iterations 500
end

tddft
rPA
nroots 10
end

task tddft energy,