Please try the following input
echo
permanent_dir /global/cscratch1/sd/apra/arar
memory stack 1300 mb heap 200 mb global 7000 mb
start im
title "im"
charge 1
geometry #units angstroms print xyz noautosym noautoz
C -2.23423902 0.59425408 -0.03224283
O -1.12129315 1.09129114 -0.09445519
O -3.30588587 0.19083810 0.02028232
Br 1.41553615 -0.39477191 0.02227492
H -0.18608027 0.45084374 -0.04234683
end
basis spherical
C library aug-cc-pvqz
H library aug-cc-pvqz
O library aug-cc-pvqz
Br library aug-cc-pvqz-pp
end
ECP
Br library aug-cc-pvqz-pp
end
scf
doublet
THRESH 1.0e-5
MAXITER 100
TOL2E 1e-12
end
tce
ccsd(t)
FREEZE atomic
tilesize 8
attilesize 12
thresh 1e-6
maxiter 100
end
task tce
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