The program automatically added hydrogens when using symmetry


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Forum Vet
When using the Cs point group, NWChem assume the mirror plane being perpendicular to the z-axis (i.e. xy plane).
Therefore, you need to rotate the molecule to satisfy this constraint as shown here

geometry
 N   0.0000   0.0000  0.0000
 H  -0.9377  -0.3816  0.0000
 H   0.4689  -0.3816  0.8121
 H   0.4689  -0.3816 -0.8121
 symmetry cs
end