Instructions in the manual cannot set modules and define target
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11:44:06 AM PDT - Fri, Jun 27th 2014
Also, if the value you're trying to set contains spaces, you need to use some sort of quotation mark.
export LIBMPI='-lmpi_f90 -lmpi_f77 -lmpi -ldl -Wl,--export-dynamic -lnsl -lutil'